G. F. Moore Lab
  • About Us
  • People
  • Projects
  • Publications
  • Media
  • Resources

Publications


At Arizona State University:​
  • Nguyen, N. P.; Hensleigh, L. K.; Nishiori, D.; Reyes Cruz, E. A.; Moore, G. F. Degrade-Repair Cycle of a Fuel-Forming Photoelectrode. ACS Appl. Energy Mater., 2022, 5, 11, 13128–13133.
 
  • Reyes Cruz, E. A.; Nishiori, D.; Wadsworth, B. L.; Nguyen, N. P.; Hensleigh, L. K.; Khusnutdinova, D.; Beiler, A. M.; Moore, G. F. Molecular-Modified Photocathodes for Applications in Artificial Photosynthesis and Solar-to-Fuel Technologies. Chem. Rev. 2022, 122, 16051–16109.
 
  • Odella, E.; Secor, M.; Reyes Cruz, E. A.; Guerra, W. D.; Urrutia, M. N.; Liddell, P. A.; Moore, T. A.; Moore, G. F.; Hammes-Schiffer, S.; Moore, A. L. Managing the Redox Potential of PCET in Grotthuss-Type Proton Wires. J. Am. Chem. Soc., 2022, 144, 15672–15679.
 
  • Arsenault, E. A.; Guerra, W. D.; Shee, J.; Reyes Cruz, E. A.; Yoneda, Y.; Wadsworth, B. L.; Odella, E.; Urrutia, M. N.; Kodis, G.; Moore, G. F.; Head-Gordon, M.; Moore, A. L.; Moore, T. A.; Fleming, G. R. Concerted Electron-Nuclear Motion in Proton-Coupled Electron Transfer-Driven Grotthuss-Type Proton Translocation. J. Phys. Chem. Lett., 2022, 13, 20, 4479–4485.
 
  • Nishiori, D.; Wadsworth, B. L.; Reyes Cruz, E. A.; Nguyen, N. P.; Hensleigh, L. K.; Karcher, T.;  Moore, G. F. Photoelectrochemistry of Metalloporphyrin-Modified GaP Semiconductors. Photosynth. Res. 2022, 151, 1-10
 
  • Nishiori, D.; Wadsworth, B. L.; Moore, G. F. Parallels Between Enzyme Catalysis, Electrocatalysis, and Photoelectrosynthesis. Chem Catalysis. 2021, 1, 978-996.
 
  • Nguyen, N. P.; Moore, G. F. Storing Sunlight at Low Temperatures? Joule. 2021, 5, 2254-2256.
 
  • Reyes Cruz, E. A.; Nishiori, D.; Wadsworth, B. L.; Khusnutdinova, D.; Karcher, T.; Landrot, G.; Lassalle-Kaiser, B.; Moore, G. F. Six-Electron Chemistry of a Binuclear Fe(III) Fused Porphyrin. ChemElectroChem. 2021, 8, 3614-3620.  
 
  • Yoneda, Y.; Mora, S. J.; Shee, J.; Wadsworth, B.; Arsenault, E.; Hait, D.; Kodis, G.; Gust, D.; Moore, G. F.; Moore, A. L. ; Head-Gordon, M.; Moore, T. A. ; Fleming, G. Electron-Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer. J. Am. Chem. Soc. 2021, 143, 3104-3112. 
 
  • Nguyen, N. P.; Wadsworth, B. L.; Nishiori, D.; Reyes Cruz, E. A.; Moore, G. F. Understanding and Controlling the Performance-Limiting Steps of Catalysts-Modified Semiconductors. J. Phys. Chem. Lett. 2021, 12, 199-203.
 
  • Guerra, W. D.; Odeella, E.;  Sector, M.;  Goings, J. J.; Wadsworth, B. L.; Gervaldo, M.; Sereno, L. E.; Moore, T. A.; Moore, G. F.; Hammes-Schiffer, S.; Moore, A. L.  Role of Intact Hydrogen-Bond Networks in Multiproton-Coupled Electron Transfer.  J. Am. Chem. Soc. 2020, 142, 21842-21851. 
 
  • Wadsworth, B. L.; Nishiori, D.; Nguyen, N. P.; Reyes Cruz, E. A.; Moore, G. F. Electrochemistry of Polymeric Cobaloxime-Containing Assemblies in Organic and Aqueous Solvents. ECS J. Solid State Sci. Technol. 2020, 9, 061018.
 
  • Wadsworth, B. L.; Nguyen, N. P.; Nishiori, D.; Beiler, A. M.; Moore, G. F. Addressing the Origin of Photocurrents and Fuel Production Activities in Catalyst-Modified Semiconductor Electrodes. ACS Appl. Energy Mater. 2020, 8, 7512-7519.
 
  • Odella, E.; Mora, S. J.; Wadsworth, B. L.; Goings, J. J.; Gervaldo, M.; Sereno, L. E.; Groy, T. L.; Gust, D.; Moore, T. A.; Moore, G. F.; Hammes-Schiffer, S.; Moore, A. L. Proton-Coupled Electron Across Benzimidazole Bridges in Bioinspired Wires. Chem. Sci. 2020, 11, 3820888-3828.
 
  • Wadsworth, B. L.; Khusnutdinova, D.; Urbine, J; Reyes, A.; Moore, G. F. Expanding the Redox Range of Surface-Immobilized Metallocomplexes using Molecular Interfaces. ACS Appl. Mater. Interfaces. 2020,12, 3903-3911.
 
  • Wadsworth, B. L.; Beiler, A. M.; Khusnutdinova, D.; Reyes Cruz, E. A.; Moore, G. F. Interplay Between Light Flux, Quantum Efficiency, and Turnover Frequency in  Molecular-Modified Photoelectrosynthetic Assemblies. J. Am. Chem. Soc. 2019, 141, 15932-15941.
 
  • Odella, E.; Wadsworth, B. L.; Mora, S. J.; Goings, J. J.; Huynh, M. T.; Gust, D.; Moore, T. A.; Moore, G. F.; Hammes-Schiffer, S.; Moore, A. L. Proton-Coupled Electron Transfer Drives Long-Range Proton Translocation in Bioinspired Systems. J. Am. Chem. Soc. 2019, 141, 14057-14061.​
 
  • Khusnutdinova, D.; Wadsworth, B. L.; Flores M.; Beiler, A. M.; Reyes Cruz, E. A.; Zenkov, Y.; Moore, G. F. Electrocatalytic Properties of Binuclear Fused Cu(II) Porphyrins for Hydrogen Evolution. ACS Catal. 2018, 8, 9888-9898.
 
  • Wadsworth, B. L.; Khusnutdinova, D.; Moore, G. F. Polymeric Coatings for Applications in Electrocatalytic and Photoelectrosynthetic Fuel Production. J. Mater. Chem. A. 2018, 6, 21654-21665.
 
  • Odell, E.; Mora, J. M.; Wadsworth, B. L.; Huynh, M. T.;  Goings J. J.; Liddel, P. A.; Groy, T. L.; Gervaldo, M.; Sereno L. E.; Gust, D.; Moore T. A.; Moore, G. F.; Hammes-Schiffer, S.; Moore, A. L. Controlling Proton-Coupled Electron Transfer in Bio-Inspired Artificial Photosynthetic Relays. J. Am. Chem. Soc. 2018, 45, 15450-15460.
 
  • Khusnutdinova, D.; Beiler, A. M.; Wadsworth, B. L.; Nanyangwe, S. K.; Moore, G. F. Vibrational Structure Analysis of Cobalt Fluoro-Porphyrin Surface Coatings on Gallium Phosphide. J. Porphyrins Phthalocyanines. 2018, 22, 461-468.
 
  • Ardo, S.; Rivas, D. F. Modestino,M.; Greiving,V. S.; Abdi, F.; Llado, E. A.; Artero, V.; Ayers, K.; Battaglia, C.; Becker, J-P.; Bederak, D.; Berger, A.; Buda, F.; Chinello, E.; Dam, B.; Palma, V. D.; Edvinsson, T.; Fujii, K. Gardeniers, H.; Geerlings, H.; Hashemi, M.; Haussener, S.; Houle, F.; Huskens,J.; James, B.; Konrad, K.; Kudo, A.; Kunturu, P. P.; Lohse, D Mei, B.; Miller, E.; Moore, G. F.; Muller, J.; Orchard, K.; Post, R.; Rosser, T.; Saadi, F.; Schüttauf, J-F.; Seger, B.; Sheehan, S.; Spurgeon, J.; Tang, M.; van de Krol, R.; Vesborg, P.; Westerik, P. Pathways to Electrochemical Solar Hydrogen Technologies. Energy Environ. Sci. 2018, 11, 2768-2783.
 
  • Mora, J. M.; Odell, E.; Gust, D.; Moore, G. F.; Moore T. A.; Moore, A. L. Proton-Coupled Electron Transfer in Artificial Photosynthetic Systems. Acc. Chem. Res. 2018, 51, 445-453. 
 
  • Beiler, A. M.; Moore, G. F. Multi-Electron Transfer Photochemistry Caught in the Act. Nature Chemistry. 2018, 1, 3-4. 
 
  • Khusnutdinova, D.; Flores, M.; Beiler, A. M.; Moore, G. F. Synthesis and Characterization of a Cobalt(II) Tetrakis(3-fluorophenyl)porphyrin with a Built-in 4-Vinylphenyl Surface Attachment Moiety. Photosynthetica. 2018, 56, 67-74. 
 
  • Beiler, A. M.; Khusnutdinova, D.; Wadsworth, B. L.; Moore, G. F. Cobalt Porphyrin-Polypyridyl Surface Coatings for Photoelectrosynthetic Hydrogen Production. Inorg. Chem. 2017, 56, 12178-12285. 
 
  • Khusnutdinova, D.; Beiler, A. M.; Wadsworth, B. L.; Jacob, S. I.; Moore, G. F. Metalloporphyrin-Modified Semiconductors for Solar Hydrogen Production. Chem. Sci. 2017, 8, 253-259.
 
  • Wadsworth, B. L.; Beiler, A. M.; Khusnutdinova, D.;Jacob, S. I.; Moore, G. F. Electrocatalytic and Optical Properties of Cobaloxime Catalysts Immobilized at a Surface-Grafted Polymer Interface. ACS Catalysis. 2016, 6, 8048-8057. 
 
  • Beiler, A. M.; Khusnutdinova, D.; Jacob, S. I.; Moore, G. F. Chemistry at the Interface: Polymer-Functionalized GaP Semiconductors for Solar Hydrogen Production. Ind. Eng. Chem. Res.  2016, 8, 10038-10043. 
 
  • Beiler, A. M.; Khusnutdinova, D.; Jacob, S. I.; Moore, G. F. Solar Hydrogen Production using Molecular Catalysts Immobilized on Gallium Phosphide (111)A and (111)B Polymer-Modified Photocathodes. ACS Appl. Mater. Interfaces. 2016, 55, 5306-5314.
 
  • Moore, G. F. Concluding Remarks and Future Perspectives, Chapter 20 of Photosynthesis: Structures, Mechanisms, and Applications. edited by  Harvey J. M. Hou, Mohammad Mahdi Najafpour, Gary F. Moore and Suleyman I. Allakhverdiev, Springer International Publishing, 2016.
 
  • Cedeno, D.; Krawicz, A.; Moore, G. F. Hybrid Photocathodes for Solar Fuel Production: Coupling Molecular Fuel-Production Catalysts with Solid-State Light Harvesting and Conversion Technologies. Interface Focus. 2015, 5, 20140085.​
 
  • Ravensbergen, J.; Brown, C. L.; Moore, G. F.; Frese R. N.; van Grondelle, R.; Gust, D.; Moore; T. A.; Moore, A. L.; Kennis, J. T. M. Kinetic Isotope Effect of Proton-Coupled Electron Transfer in a Hydrogen Bonded Phenol–Pyrrolidino[60]fullerene. Photochem. Photobiol. Sci. 2015, 14, 2147-2150.
 
  • Cedeno, D.; Krawicz, A.; Doak, P.; Yu, M.; Neaton, J. B.; Moore, G. F. Using Molecular Design to Control the Performance of Hydrogen-Producing Polymer-Brush-Modified Photocathodes. J. Phys. Chem. Lett. 2014, 5, 3222-3226.

At Berkeley Lab:
  • Krawicz, A.; Cedeno, D.; Moore, G. F. Energetics and Efficiency Analysis of a Cobaloxime-Modified Semiconductor at Simulated Air Mass 1.5 Illumination. Phys. Chem. Chem. Phys. 2014, 16, 15818-15824 (Cover Article). 
 
  • Krawicz, A.; Yang, J.; Anzenberg, E.; Yano, J.; Sharp, I. D.; Moore, G. F. Photofunctional Construct That Interfaces Molecular Cobalt-Based Catalysts for H2 Production to a Visible-Light-Absorbing Semiconductor. J. Am. Chem. Soc. 2013, 135, 11861-11868.
 
  • Faunce, T. A.; Lubitz, W.; Rutherford, A. W.; MacFarlane D.; Moore, G. F.; Yang, P.; Nocera, D. G.; Moore, T. A.; Gregory, D. H.; Fukuzumi, S.; Yoon, K. B.; Armstrong, F. A.; Wasielewski, M. R. Energy and Environment Policy Case for a Global Project on Artificial Photosynthesis. Energy Environ. Sci. 2013, 6, 695-698.
 
  • Moore, G. F.; Sharp, I. D. A Noble-Metal-Free Hydrogen Evolution Catalyst Grafted to Visible Light-Absorbing Semiconductors. J. Phys. Chem. Lett. 2013, 13, 568-572.   
 
  • Ugeda, M.; Yu, M.; Bradley, A.; Doak, P.; Liu, W.; Moore, G. F.; Sharp, I.; Tilley, T. D.; Neaton, J.; Crommie, M. Adsorption and Stability of π-Bonded Ethylene on GaP(110). J. Phys. Chem. C. 2013, 117, 26091-26096.
 
  • Moore, G. F. Molecular and Nanoscale Interfaces for a Global Scale Challenge. European Photochemical Society Newsletter. 2013, July, 91-92.
 
  • Krawicz, A.; Moore, G. F. GATR-FTIR Characterization of Cobaloxime Modified p-Type Gallium Phosphide Cathodes. Prepr. Pap.-Am. Chem. Soc., Div. Energy Fuels 2013, 58 (2), 177-178.
 
  • Najafpour, M. M.; Shen, J-R.; Barber, J.; Moore, G. F.; Govindjee Running on Sun. Chemistry World. 2012, November, 43.


Prior to Arizona State University and Berkeley Lab:
  • Milot, R. L.; Moore, G. F.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 Nanoparticles.  J. Phys. Chem. C. 2013,117, 21662-21670. 
 
  • Martini, A. L.; Moore, G. F. Milot, R. L.; Cai, L. Z.; Sheehan, S. W.; Schmuttenmaer, C. A.; Brudvig, G. W.; Crabtree, R. H. Modular Assembly of High-Potential Zinc Porphyrin Photosensitizers Attached to TiO2 with a Series of Anchoring Groups. J. Phys. Chem. Lett. 2013, 117, 14526-14533.
 
  • Milot, Rebecca L.; Moore, G. F.; Richter, C.; Martini, A. L.; Negre, C. A.; Batista, V. S.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Using Time-Resolved THz Spectroscopy to Study Carrier Dynamics and Solar Energy Conversion in TiO2 Nanotubes and Other Nanostructured Materials. Abstracts of Papers, 246th ACS National Meeting & Exposition. 2013, pp COLL-421.
 
  • Moore, G. F.; Konezny, S. J.; Song, H.; Milot, R. L.; Blakemore, J. D.; Lee, M. L.; Batista, V. S.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. Bioinspired High-Potential Porphyrin Photoanodes. J. Phys . Chem. C. 2012, 116 , 4892-4902. 
 
  • Moore, G. F.; Ananyev, G. M.; Govindjee Young Research Investigators Honored at 2012 Gordon Research Conference on Photosynthesis. Photosynth. Res. 2012, 114, 137-142. 
 
  • Moore, GF; Megiatto, JD; Hambourger, M .; Gervaldo, M .; Kodis, G.; Gust, D .; Moore, TA; Moore, AL Optical and Electrochemical Properties of Hydrogen-Bonded Phenol-Pyrrolidino[60]Fullerenes. Photochem. Photobiol. Sci. 2012, 6, 1018-1025.   
 
  • Milot, Rebecca L.; Richter, C.; Moore, G. F.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Time Resolved THz Spectroscopy to Study Carrier Injection and Dynamics in TiO2 and SnO2. Abstracts of Papers, 243rd ACS National Meeting & Exposition. 2012, pp FUEL-466.
 
  • Moore, G. F.; Blakemore, J. D.; Milot, R. L.; Hull, J.; Song, H.; Cai, L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. A Visible Light Water Splitting Cell with a Photoanode Formed by Code Position of a High-Potential Porphyrin and a Homogeneous Iridium Water Oxidation Catalyst. Energy Environ. Sci. 2011, 4, 2389-2892.
 
  • Moore, G. F.; Brudvig, G. W. Energy Conversion in Photosynthesis: A Paradigm for Solar Fuel Production. Annu. Rev. Condens. Matter Phys. 2011, 2, 303-327.
 
  • Schmuttenmaer, C. A.; Richter, C.; Milot, R. L.; Moore, G. F.; Brudvig, G. W. Using Time Resolved THz Spectroscopy to Study Carrier Injection and Dynamics in TiO2 and SnO2. Abstracts of Papers, 242nd ACS National Meeting. 2011, pp COMP-69.
 
  • Moore, G. F.; Hambourger, M.; Kodis, G.; Michl, W.; Gust, D.; Moore, T. A.; Moore, A. L. Effects of Protonation State on a Tyrosine-Histidine Bioinspired Mediator. J. Phys. Chem. B. 2010, 114, 14450-14457. 
​
  • Hambourger, M.; Kodis, G.; Vaugnh, M.; Moore, G. F.; Gust, D.; Moore, A. L.; Moore, T. A. Solar Energy Conversion in a Photoelectrochemical Biofuel Cell. Dalton Transactions. 2009, 45, 9979-9989.
 
  • Hambourger, M.; Moore, G. F.; Kramer, D. M.; Gust, D.; Moore, A. L.; Moore, T. A. Biology and Technology for Photochemical Fuel Production. Chem. Soc. Rev. 2009, 38, 25-35.  ​
 
  • Moore, G. F.; Hambourger, M.; Gervaldo, M.; Poluektov, O. G.; Rajh, T.; Gust, D.; Moore, T. A.; Moore, A. L. A A Bioinspired Construct that Mimics the Proton Coupled Electron Transfer between P680 and the TyrZ-His190 Pair of Photosystem II. J. Am. Chem. Soc. 2008, 130, 10466-10467.
 
  • Rizzi, A., van Gastel, M., Liddell, P. A., Palacios, RE, Moore, G. F., Codice, G., Moore, AL, Moore, T. A., GUST, D., Braslavsky, S.E. Entropic Changes Control the Charge Separation Process in Triads Mimicking Photosynthetic Charge Separation. J. Phys. Chem. A. 2008, 112, 4215-4223.
 
  • Moore, T. A.; Moore, A. L.; Gust, D.; Hambourger, M.; Moore, G. F.; Keirstead, A.; Gervaldo, M. Artificial Photosynthesis: Combining Technology with Biology for Efficient Solar Energy Conversion. Abstracts of Papers, 235th ACS National Meeting. 2008​, pp IEC-011.
 
  • Moore, A. L.; Moore, G. F.; Hambourger, M.; Kodis, G.; Gervaldo, M.; Liddell, P.A.; Gust, D.; Moore, T. A. Bioinspired Energy Conversion Schemes. Abstracts of Papers, 233rd ACS National Meeting. 2007, pp INOR-088th.
 
  • Berera, R.; Moore, G. F.; Stokkum, I. H. M.; Kodis, G.; Liddell, P. A.; Gervaldo, M.; van Grondelle, R.; Kennis, J. T. M.; Gust, D.; Moore, T. A.; Moore, A. L. Charge Separation and Energy Transfer in a Caroteno-C60 dyad: Photoinduced Electron Transfer From the carotenoid Excited States. Photochem. Photobiol. Sci. 2006, 5, 1142-1149 (Cover Article).
 
  • Moore, A. L.; Moore, T. A.; Gust, D.; Moore, G. F.; Kennis, J.; Hambourger, M .; Kodis, G.; Liddell, P. A. Energy Conversion Involving Carotenoids Polyenes. Abstracts of Papers, 230th ACS National Meeting. 2005​, pp PHYS-193rd.
​
  • Pessiki, P. J.; Moore, G. F. Synthesis and Photochemical Properties of Tetraphenylporphyrins Covalently Attached to Lichen Acids. Abstracts of Papers, 228th ACS National Meeting. 2004, pp ORGN-490.
Picture
G. F. Moore Lab
Interdisciplinary Science and Technology Building V
Arizona State University 
Tempe, AZ 85287
Email:
gfmoore@asu.edu